Photodissociation of the OD radical at 226 and 243 nm
نویسندگان
چکیده
The photodissociation dynamics of state selected OD radicals has been examined at 243 and 226 nm using velocity map imaging to probe the angle–speed distributions of the D(S) and O(P2) products. Both experiment and complementary first principle calculations demonstrate that photodissociation occurs by promotion of OD from high vibrational levels of the ground X P state to the repulsive 1 S state. © 2003 American Institute of Physics. @DOI: 10.1063/1.1623175#
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